Search results for "Ethyl trifluoropyruvate"

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ChemInform Abstract: Organocatalytic Enantioselective Friedel-Crafts Alkylation of 1-Naphthol Derivatives and Activated Phenols with Ethyl Trifluorop…

2016

Financial support from the MINECO [Gobierno de Espana and FEDER (EU)] (CTQ2013-47949-P) and from Generalitat Valenciana (ISIC2012/001) is gratefully acknowledged. M.M.-M. thanks the Universitat de Valencia for a predoctoral grant. C. V. thanks MINECO for JdC contract. Access to NMR and MS facilities from the Servei central de support a la investigacio experimental (SCSIE)-UV is also acknowledged.

Ethyl trifluoropyruvatechemistry.chemical_compoundchemistrybiology1-NaphtholOrganocatalysisEnantioselective synthesisOrganic chemistryGeneral MedicinePhenolsbiology.organism_classificationValenciaFriedel–Crafts reactionChemInform
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Organocatalytic Enantioselective Friedel-Crafts Alkylation of 1-Naphthol Derivatives and Activated Phenols with Ethyl Trifluoropyruvate

2015

An organocatalytic enantioselective Friedel–Crafts alkylation of a series of substituted 1- naphthol derivatives and activated phenols with ethyl trifluoropyruvate, catalyzed by a quinine-derived squaramide, is presented. Good yields and high to excellent enantioselectivities of the Friedel– Crafts alkylation products were obtained.

biologyOrganocatalysis1-NaphtholEnantioselective synthesisGeneral ChemistryNaphtholsbiology.organism_classificationTrifluoropyruvatesReaccions químiqueschemistry.chemical_compoundEthyl trifluoropyruvatechemistryCatàlisiOrganocatalysisFISICA APLICADAAsymmetric catalysisOrganic chemistryPhenolsValenciaFriedel–Crafts reactionQuímica orgànicaFriedel–Crafts reaction
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